http://www.codeguru.com/csharp/csharp/net30/article.php/c13799
http://www.dnrtv.com/archives.aspx
http://www.codeplex.com/AutoMapper
http://www.dimecasts.net/Casts/ByTag/ReSharper
Essentially the C# 4.0 language innovations include:
http://software.intel.com/en-us/blogs/2009/03/30/the-c-programming-language-version-40/
... and more syntactic sugar.. :-)